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Alloying Pd with Ru enables electroreduction of nitrate to ammonia with ∼100% faradaic efficiency over a wide potential window

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC00558A, Edge Article
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Yue Hu, Jiawei Liu, Wenyu Luo, Jinfeng Dong, Carmen Lee, Nan Zhang, Mengxin Chen, Yifan Xu, Dongshuang Wu, Mingsheng Zhang, Qiang Zhu, Erhai Hu, Dongsheng Geng, Lixiang Zhong, Qingyu Yan
A designed Pd74Ru26 achieved a high-level dynamic equilibrium of adsorption and coupling between *H and various nitrogen intermediates during eNO3RR.
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Formation of compounds with diverse polyelectrolyte morphologies and nonlinear ion conductance in a two-dimensional nanofluidic channel

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC01071J, Edge Article
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Xiaoying Liang, Yanan Zhou, Weiduo Zhu, Wen Wu Xu, Joseph S. Francisco, Xiao Cheng Zeng, Wenhui Zhao
Our molecular dynamics simulations revealed diverse polyelectrolyte morphologies in angstrom-scale slits, resulting in intriguing gating effects and nonlinear ionic conductance.
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The importance of understanding (pre)catalyst activation in versatile C−H bond functionalisations catalysed by [Mn2(CO)10]

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC01215A, Edge Article
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Jonathan B. Eastwood, Thomas J Burden, Lars Anders Hammarback, Chris S. Horbaczewskyj, Theo Tanner, Ian P Clark, Gregory M Greetham, Michael Towrie, Ian J. S. Fairlamb, Jason Martin Lynam
Mn-catalysed reactions offer great potential in synthetic organic and organometallic chemistry and the success of Mn carbonyl complexes as (pre)catalysts hinges on their stabilisation by strong field ligands enabling Mn(I)-based,...
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Investing in Entropy: The Strategy of Cucurbit[n]urils to Accelerate the Intramolecular Diels-Alder Cycloaddition Reaction of Tertiary Furfuryl Amines

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC01816H, Edge Article
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Pablo Ballester, Karen de la Vega-Hernández, Marcos G. Suero
Cucurbit[n]urils, renowned for their host-guest chemistry, are becoming versatile biomimetic receptors. Herein, we report that cucurbit[7]uril (CB[7]) accelerates the intramolecular Diels-Alder (IMDA) reaction for previously elusive and unreactive tertiary N-methyl-N-(homo)allyl-2-furfurylamines...
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Photoswitching of Co(II)-based coordination cages containing azobenzene backbones

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC01575D, Edge Article
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Max B. Tipping, Lidón Pruñonosa Lara, Atena B. Solea, Larissa K. S. von Krbek, Michael D. Ward
Inclusion of photoswitchable azobenzene units as spacers into ditopic bridging ligands Lm and Lp, containing two chelating pyrazolyl-pyridine termini, allows formation of metal complex assemblies with Co(II) that undergo a...
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Hydroalkylation of styrenes enabled by boryl radical mediated halogen atom transfer

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC01731E, Edge Article
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Serena Pillitteri, Rajat Walia, Erik V Van der Eycken, Upendra K. Sharma
In this study, we present an inexpensive, stable, and easily available boryl radical source (NaBPh4) employed in a Halogen Atom Transfer (XAT) methodology. This mild and convenient strategy unlocks the...
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